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Gator w/ Chiaroscuro Effect
I took this image at Gatorland. I was fascinated by the way water drops seemed to dance on top of the Gators back as he did his display. I added some dark lighting effect and tried to replicate the Chiaroscuro look for the theme.
I added a new layer to my image and filled it w/ 80% black. It is important to choose the image carefully, some will not lend themselves nicely to this look. Then I added a layer mask and at a low opacity started brushing on the light where I wanted it. I fine tuned it w/ a non-destructive dodge and burn. I think I learned a lot about this effect and would do it a bit differently. This can help you get started. :)